| 词条 | Rhenium(VI) chloride |
| 释义 |
| ImageFile = ReCl6.png | ImageSize = 128 | ImageAlt = | IUPACName = | OtherNames = rhenium hexachloride |Section1={{Chembox Identifiers | CASNo = 31234-26-1 | PubChem = | ChemSpiderID = 4321528 | SMILES = Cl[Re](Cl)(Cl)(Cl)(Cl)Cl | StdInChI=1S/6ClH.Re/h6*1H;/q;;;;;;+6/p-6 | StdInChIKey=GSGIQJBJGSKCDZ-UHFFFAOYSA-H }} |Section2={{Chembox Properties | Cl=6|Re=1 | MolarMass = | Appearance = black solid | Density = | MeltingPt = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }}Rhenium(VI) chloride is the inorganic compound with the formula ReCl6. It is a black paramagnetic solid. The molecules adopt an octahedral structure as seen in tungsten(VI) chloride.[1] Preparation and reactionsRhenium(VI) chloride is prepared from the rhenium hexafluoride with excess boron trichloride: 2 ReF6 + 6 BCl3 → ReCl6 + 6 BF2Cl It is unstable at room temperature with respect to rhenium(V) chloride: 2 ReCl6 → [ReCl5]2 + Cl2 References1. ^{{cite journal|authors=Tamadon, Farhad; Seppelt, K., |title=The Elusive Halides VCl5, MoCl6, and ReCl6|journal=Angewandte Chemie International Edition|year=2012|volume=52|pages=767-769|doi=10.1002/anie.201207552}} {{Rhenium compounds}} 3 : Rhenium compounds|Chlorides|Metal halides |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。