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词条 Vinyldiphenylphosphine
释义

  1. References

{{Chembox
| ImageFile = VinylPPh2.png
| ImageSize =
| ImageAlt =
| IUPACName = ethenyl(diphenyl)phosphane
| OtherNames = Diphenylvinylphosphine
|Section1={{Chembox Identifiers
| CASNo = 2155-96-6
| PubChem = 75083
| ChemSpiderID = 67635
| EINECS = 218-459-2
| InChI = 1S/C14H13P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h2-12H,1H2
| InChIKey = AJVBXLXLODZUME-UHFFFAOYSA-N
| SMILES = C=CP(C1=CC=CC=C1)C2=CC=CC=C2 }}
|Section2={{Chembox Properties
| C=14|H=13|P=1
| MolarMass =
| Appearance = colorless solid
| Density =
| MeltingPtC = 70.5-71.5
| BoilingPtC = 104
| Solubility = }}
|Section3={{Chembox Hazards
| MainHazards =
| FlashPt =
| AutoignitionPt = }}
}}Vinyldiphenylphosphine is the organophosphorus compound with the formula (C6H5)2PCH=CH2. This colorless, air-sensitive solid is used as a precursor to ligands used in coordination chemistry and homogeneous catalysis. It is prepared by treating chlorodiphenylphosphine with vinyl Grignard reagents.[1]

References

1. ^{{cite journal|title=Phosphorus-containing monomers. I. Synthesis of Vinyl Phosphines, Oxides, Sulfides, and Phosphonium Compounds|authors=Rabinowitz, Robert; Pellon, Joseph|journal=Journal of Organic Chemistry|year=1961|volume=26|issue=11|pages=4623–6|doi=10.1021/jo01069a101}}

3 : Tertiary phosphines|Phenyl compounds|Vinyl compounds

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