词条 | Vinyldiphenylphosphine |
释义 |
| ImageFile = VinylPPh2.png | ImageSize = | ImageAlt = | IUPACName = ethenyl(diphenyl)phosphane | OtherNames = Diphenylvinylphosphine |Section1={{Chembox Identifiers | CASNo = 2155-96-6 | PubChem = 75083 | ChemSpiderID = 67635 | EINECS = 218-459-2 | InChI = 1S/C14H13P/c1-2-15(13-9-5-3-6-10-13)14-11-7-4-8-12-14/h2-12H,1H2 | InChIKey = AJVBXLXLODZUME-UHFFFAOYSA-N | SMILES = C=CP(C1=CC=CC=C1)C2=CC=CC=C2 }} |Section2={{Chembox Properties | C=14|H=13|P=1 | MolarMass = | Appearance = colorless solid | Density = | MeltingPtC = 70.5-71.5 | BoilingPtC = 104 | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }}Vinyldiphenylphosphine is the organophosphorus compound with the formula (C6H5)2PCH=CH2. This colorless, air-sensitive solid is used as a precursor to ligands used in coordination chemistry and homogeneous catalysis. It is prepared by treating chlorodiphenylphosphine with vinyl Grignard reagents.[1] References1. ^{{cite journal|title=Phosphorus-containing monomers. I. Synthesis of Vinyl Phosphines, Oxides, Sulfides, and Phosphonium Compounds|authors=Rabinowitz, Robert; Pellon, Joseph|journal=Journal of Organic Chemistry|year=1961|volume=26|issue=11|pages=4623–6|doi=10.1021/jo01069a101}} 3 : Tertiary phosphines|Phenyl compounds|Vinyl compounds |
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