| 词条 | Calone |
| 释义 |
| ImageFile = Calone V1.svg | ImageSize = 200px | IUPACName = 7-Methylbenzo[b][1,4]dioxepin-3-one | OtherNames = Calone 1951; Watermelon ketone; Methylbenzodioxepinone |Section1={{Chembox Identifiers | ChemSpiderID = 107218 | InChI = 1/C10H10O3/c1-7-2-3-9-10(4-7)13-6-8(11)5-12-9/h2-4H,5-6H2,1H3 | InChIKey = SWUIQEBPZIHZQS-UHFFFAOYAC | CASNo = 28940-11-6 | PubChem = 120101 | SMILES = O=C1COc2c(OC1)cc(cc2)C }} |Section2={{Chembox Properties | C=10 | H=10 | O=3 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = }} |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }} }} Calone or methylbenzodioxepinone, trade-named Calone 1951, also known in the industry as "watermelon ketone", was discovered by Pfizer in 1966. It is used to give the olfactory impression of a fresh seashore through the marine and ozone nuances. Calone is similar in structure of certain alicyclic C11-hydrocarbons like ectocarpene, excreted by some species of brown algae as pheromones. Calone is an unusual odorant which has an intense "sea-breeze" note with slight floral overtones. It has been used as a scent component since the 1980s for its watery, fresh, ozone accords, and as a more dominant note in several perfumes of the marine trend, beginning in the 1990s. In 2014, Plummer and co-workers reported the synthesis and fragrance properties of several related aliphatic analogues. [1] References1. ^{{cite journal | title = Synthesis of Saturated Benzodioxepinone Analogues: Insight into the Importance of the Aromatic Ring Binding Motif for Marine Odorants | author = C. M. Plummer, R. Gericke, P. Kraft, A. Raynor, J. Froese, T. Hudlicky, T. J. Rook, O. A. H. Jones and H. M. Hϋgel | journal = Eur. J. Org. Chem. | date = 4 Dec 2014 | volume=2015 | pages=486–495 | doi=10.1002/ejoc.201403142}} External links
2 : Perfume ingredients|Ketones |
| 随便看 |
|
开放百科全书收录14589846条英语、德语、日语等多语种百科知识，基本涵盖了大多数领域的百科知识，是一部内容自由、开放的电子版国际百科全书。