| 词条 | Gallium(III) iodide |
| 释义 |
| Verifiedfields = changed | Watchedfields = changed | verifiedrevid = 476993585 | Name = Gallium(III) iodide | ImageFile = Gallium-iodide-3D-balls.png | ImageName = Gallium(III) iodide | OtherNames = gallium triiodide |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 75316 | InChI = 1/Ga.3HI/h;3*1H/q+3;;;/p-3 | InChIKey = DWRNSCDYNYYYHT-DFZHHIFOAW | SMILES = I[Ga](I)I | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/Ga.3HI/h;3*1H/q+3;;;/p-3 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = DWRNSCDYNYYYHT-UHFFFAOYSA-K | CASNo_Ref = {{cascite|changed|??}} | CASNo = 13450-91-4 | PubChem = 83478 |Section2={{Chembox Properties | Formula = GaI3 | MolarMass = 450.436 g/mol | Appearance = light yellow powder | Density = 4.15 g/cm3 | Solubility = decomposes | MeltingPtC = 212 | BoilingPtC = 345 | MagSus = −149.0·10−6 cm3/mol |Section7={{Chembox Hazards | EUClass = not listed | NFPA-H = 4 | NFPA-R = 1 | NFPA-F = 0 }}Gallium(III) iodide is the chemical compound with the formula GaI3. It is the most common iodide of gallium. In the chemical vapor transport method of growing crystals of gallium arsenide uses iodine as the transport agent. It also exists as a dimer , Ga2I6.[1] Gallium triiodide can be reduced with gallium metal to give a green-colored solid called "gallium(I) iodide." The nature of this species is unclear, but it is useful for the preparation of compounds of gallium(I) and gallium(II) and is reported as useful in organic syntheses.[2][3] References1. ^C. Brünig, S. Locmelis, E. Milke, M. Binnewies, "Chemischer Transport fester Lösungen. 27. Mischphasenbildung und chemischer Transport im System ZnSe/GaAs" Zeitschrift für anorganische und allgemeine Chemie 2006, 632, 6 , 1067 - 1072. {{doi|10.1002/zaac.200600008}} 2. ^Baker, Robert J.; Jones, Cameron. ""GaI": A versatile reagent for the synthetic chemist" Dalton Transactions (2005), (8), pp. 1341-1348. {{doi|10.1039/b501310k}} 3. ^GaI: A new reagent for chemo- and diastereoselective C–C bond forming reactions, Green SP, Jones C., Stasch A., Rose R.P, New J. Chem., 2007, 31, 127 - 134, {{doi|10.1039/b613669a}} See also
4 : Iodides|Gallium compounds|Metal halides|Inorganic compound stubs |
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