“Lead telluride”的意思、由来-开放百科全书

Lead telluride is a compound of lead and tellurium (PbTe). It crystallizes in the NaCl crystal structure with Pb atoms occupying the cation and Te forming the anionic lattice. It is a narrow gap semiconductor with a band gap of 0.32 eV.^[3] It occurs naturally as the mineral altaite.

Properties

Applications

PbTe has proven to be a very important intermediate thermoelectric material. The performance of thermoelectric materials can be evaluated by the figure of merit,

, in which

is the Seebeck coefficient,

is the electrical conductivity and

is the thermal conductivity. In order to improve the thermoelectric performance of materials, the power factor (

) needs to be maximized and the thermal conductivity needs to be minimized.^[4]

The PbTe system can be optimized for power generation applications by improving the power factor via band engineering. It can be doped either n-type or p-type with appropriate dopants. Halogens are often used as n-type doping agents. PbCl2, PbBr2 and PbI2 are commonly used to produce donor centers. Other n-type doping agents such as Bi2Te3, TaTe2, MnTe2, will substitute for Pb and create uncharged vacant Pb-sites. These vacant sites are subsequently filled by atoms from the lead excess and the valence electrons of these vacant atoms will diffuse through crystal. Common p-type doping agents are Na2Te, K2Te and Ag2Te. They substitute for Te and create vacant uncharged Te sites. These sites are filled by Te atoms which are ionized to create additional positive holes.^[5] With band gap engineering, the maximum zT of PbTe has been reported to be 0.8 - 1.0 at ~650K.

Collaborations at Northwestern University boosted the zT of PbTe by significantly reducing its thermal conductivity using ‘all-scale hierarchical architecturing'.^[6] With this approach, point defects, nanoscale precipitates and mesoscale grain boundaries are introduced as effective scattering centers for phonons with different mean free paths, without affecting charge carrier transport. By applying this method, the record value for zT of PbTe that has been achieved in Na doped PbTe-SrTe system is approximately 2.2.^[7]

In addition, PbTe is also often alloyed with tin to make lead tin telluride, which is used as an infrared detector material.

See also

References

1. ^{{Citation | last = Lide | first = David R. | year = 1998 | title = Handbook of Chemistry and Physics | edition = 87 | location = Boca Raton, Florida | publisher = CRC Press | isbn = 978-0-8493-0594-8 |ref={{harvid|CRC Handbook}} | pages = 4–65}}
2. ^{{Cite journal | last = Lawson | first = William D | year = 1951 | title = A method of growing single crystals of lead telluride and selenide | volume = 22 | issue = 12 | doi = 10.1063/1.1699890 | pages = 1444–1447 | journal = J. Appl. Phys.}}
3. ^{{Cite journal|title = Nanostructured Thermoelectrics: The New Paradigm? †|journal = Chemistry of Materials|date = 2009-10-07|pages = 648–659|volume = 22|issue = 3|doi = 10.1021/cm902195j|first = Mercouri G.|last = Kanatzidis}}
4. ^{{Cite journal |title = High performance bulk thermoelectrics via a panoscopic approach|url = http://www.sciencedirect.com/science/article/pii/S136970211300151X|journal = Materials Today|date = 2013-05-01|pages = 166–176|volume = 16|issue = 5|doi = 10.1016/j.mattod.2013.05.004|first = Jiaqing|last = He|first2 = Mercouri G.|last2 = Kanatzidis|first3 = Vinayak P.|last3 = Dravid}}
5. ^{{Cite journal |title = Lead telluride as a thermoelectric material for thermoelectric power generation|url = http://www.sciencedirect.com/science/article/pii/S0921452602011870|journal = Physica B: Condensed Matter|date = 2002-09-01|pages = 205–223|volume = 322|issue = 1–2|doi = 10.1016/S0921-4526(02)01187-0|first = Z. H.|last = Dughaish}}
6. ^{{Cite journal|title = Strained endotaxial nanostructures with high thermoelectric figure of merit|url = http://www.nature.com/nchem/journal/v3/n2/abs/nchem.955.html|journal = Nature Chemistry|date = 2011-02-01|issn = 1755-4330|pages = 160–166|volume = 3|issue = 2|doi = 10.1038/nchem.955|first = Kanishka|last = Biswas|first2 = Jiaqing|last2 = He|first3 = Qichun|last3 = Zhang|first4 = Guoyu|last4 = Wang|first5 = Ctirad|last5 = Uher|first6 = Vinayak P.|last6 = Dravid|first7 = Mercouri G.|last7 = Kanatzidis|pmid=21258390}}
7. ^{{Cite journal|title = High-performance bulk thermoelectrics with all-scale hierarchical architectures|url = http://www.nature.com/nature/journal/v489/n7416/abs/nature11439.html|journal = Nature|date = 2012-09-20|issn = 0028-0836|pages = 414–418|volume = 489|issue = 7416|doi = 10.1038/nature11439|first = Kanishka|last = Biswas|first2 = Jiaqing|last2 = He|first3 = Ivan D.|last3 = Blum|first4 = Chun-I.|last4 = Wu|first5 = Timothy P.|last5 = Hogan|first6 = David N.|last6 = Seidman|first7 = Vinayak P.|last7 = Dravid|first8 = Mercouri G.|last8 = Kanatzidis|pmid=22996556}}

Properties

Applications

See also

References

External links