词条 | Erythrose |
释义 |
| verifiedrevid = 450917285 | Reference = [1] | ImageFile1 = D-erythrose.svg | ImageSize1 = 150px | ImageCaption1 = D-Erythrose | ImageFile2 = L-erythrose.svg | ImageSize2 = 150px | ImageCaption2 = L-Erythrose | IUPACName = (2R,3R)-2,3,4-Trihydroxybutanal (D) (2S,3S)-2,3,4-Trihydroxybutanal (L) | OtherNames = |Section1={{Chembox Identifiers | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 84990 | ChemSpiderID_Comment = (D) | InChI = 1/C4H8O4/c5-1-3(7)4(8)2-6/h1,3-4,6-8H,2H2/t3-,4+/m0/s1 | InChIKey = YTBSYETUWUMLBZ-IUYQGCFVBI | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C4H8O4/c5-1-3(7)4(8)2-6/h1,3-4,6-8H,2H2/t3-,4+/m0/s1 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = YTBSYETUWUMLBZ-IUYQGCFVSA-N | CASNo = 583-50-6 | CASNo_Ref = {{cascite|correct|CAS}} | CASNo_Comment = (D) | CASNo1 = 533-49-3 | CASNo1_Ref = {{cascite|correct|CAS}} | CASNo1_Comment = (L) | PubChem = 94176 | PubChem_Comment = (D) | ChEBI_Ref = {{ebicite|correct|EBI}} | ChEBI = 27904 | SMILES = OC[C@@H](O)[C@@H](O)C=O | SMILES_Comment = (D) | SMILES1 = OC[C@H](O)[C@H](O)C=O | SMILES1_Comment = (L) |Section2={{Chembox Properties | C=4|H=8|O=4 | Appearance = Light yellow syrup | Density = | MeltingPt = | BoilingPt = | Solubility = Very soluble |Section3={{Chembox Hazards | NFPA-H = 1 | NFPA-F = 1 | NFPA-R = 0 | MainHazards = | FlashPt = | AutoignitionPt = }} Erythrose is a tetrose saccharide with the chemical formula C4H8O4. It has one aldehyde group, and so is part of the aldose family. The natural isomer is D-erythrose. Erythrose was first isolated in 1849 from rhubarb by the French pharmacist Louis Feux Joseph Garot (1798-1869),[2] and was named as such because of its red hue in the presence of alkali metals (ἐρυθρός, "red").[3][4] Erythrose 4-phosphate is an intermediate in the pentose phosphate pathway[5] and the Calvin cycle.[6]Oxidative bacteria can be made to use erythrose as its sole energy source.[7] See alsoErythritolReferences1. ^Merck Index, 11th Edition, 3637 {{Carbohydrates}}2. ^[https://books.google.com/books?id=L_tBAAAAcAAJ&pg=PA472#v=onepage&q&f=false Obituary of Garot] (1869) Journal de pharmacie et de chimie, 4th series, 9 : 472-473. 3. ^Garot (1850) [https://books.google.com/books?id=2bQ8AAAAcAAJ&pg=PA5#v=onepage&q&f=false "De la matière colorante rouge des rhubarbes exotiques et indigènes et de son application (comme matière colorante) aux arts et à la pharmacie"] (On the red coloring material of exotic and indigenous rhubarb and on its application (as a coloring material) in the arts and in pharmacy), Journal de Pharmacie et de Chimie, 3rd series, 17 : 5-19. Erythrose is named on p. 10: "Celui que je propose, sans y attacher toutefois la moindre importance, est celui d'érythrose, du verbe grec 'ερυθραινω, rougir (1)." (The one [i.e., name] that I propose, without attaching any importance to it, is that of erythrose, from the Greek verb ερυθραινω, to redden (1).) 4. ^{{cite book|last1=Wells|first1=David Ames|last2=Cross|first2=Charles Robert|last3=Bliss|first3=George|last4=Trowbridge|first4=John|last5=Nichols|first5=William Ripley|last6=Kneeland|first6=Samuel|title=Annual of Scientific Discovery|date=1851|publisher=Gould, Kendall, and Lincoln|location=Boston|page=211|url=https://books.google.com/?id=TBc1AAAAMAAJ&dq=erythrose+discovery|accessdate=11 December 2014}} 5. ^{{cite journal|last1=Kruger|first1=Nicholas J|last2=von Schaewen|first2=Antje|title=The oxidative pentose phosphate pathway: structure and organisation|journal=Current Opinion in Plant Biology|date=June 2003|volume=6|issue=3|pages=236–246|doi=10.1016/S1369-5266(03)00039-6}} 6. ^{{cite journal|last1=Schwender|first1=Jörg|last2=Goffman|first2=Fernando|last3=Ohlrogge|first3=John B.|last4=Shachar-Hill|first4=Yair|title=Rubisco without the Calvin cycle improves the carbon efficiency of developing green seeds|journal=Nature|date=9 December 2004|volume=432|issue=7018|pages=779–782|doi=10.1038/nature03145|pmid=15592419}} 7. ^{{cite journal|last1=Hiatt|first1=Howard H|last2=Horecker|first2=B L|title=D-erythrose metabolism in a strain of Alcaligenes faecalis|journal=Journal of Bacteriology|date=13 October 1955|volume=71|issue=6|pages=649–654|url=http://jb.asm.org/content/71/6/649.long|accessdate=11 December 2014}} 1 : Aldotetroses |
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