词条 | Trifluoromethylisocyanide |
释义 |
| Verifiedfields = changed | verifiedrevid = 470614562 | ImageFile = Trifluoromethyl isocyanide.svg | ImageSize = 160 | ImageAlt = Skeletal formula | ImageFile1 = Trifluoromethyl-isocyanide-3D-spacefill.png | ImageSize1 = 150 | ImageAlt1 = Space-filling model | IUPACName = trifluoro(isocyano)methane | OtherNames = trifluoro-methyl-azaniumylidyne methane |Section1={{Chembox Identifiers | InChI = 1/C2F3N/c1-6-2(3,4)5 | InChIKey = LKHQVUSYAMWNQZ-UHFFFAOYAU | StdInChI_Ref = {{stdinchicite|correct|chemspider}} | StdInChI = 1S/C2F3N/c1-6-2(3,4)5 | StdInChIKey_Ref = {{stdinchicite|correct|chemspider}} | StdInChIKey = LKHQVUSYAMWNQZ-UHFFFAOYSA-N | CASNo_Ref = {{cascite|changed|??}} | CASNo = 105879-13-8 | PubChem = 145434 | ChemSpiderID_Ref = {{chemspidercite|correct|chemspider}} | ChemSpiderID = 128288 | SMILES = [C-]#[N+]C(F)(F)F |Section2={{Chembox Properties | Formula = CF3NC | MolarMass = 95.023 | Appearance = | Density = | MeltingPt = | BoilingPt = | Solubility = |Section3={{Chembox Hazards | MainHazards = | FlashPt = | AutoignitionPt = }}Trifluoromethylisocyanide is the chemical compound with the formula CF3NC. It is an isocyanide and a fluorocarbon. Polymerisation occurs even at temperatures below its boiling point of -80 °C. As a ligand in coordination chemistry, this species behaves similarly to carbon monoxide.[1] The compound trifluoracetonitrile (CF3CN) is an isomer to trifluoromethylisocyanide. The nitrile is more stable, as is the usual case. References1. ^{{cite journal| author=D. Lentz|title= Fluorinated Isocyanides - More than Ligands with Unusual Properties |journal= Angewandte Chemie International Edition in English|year= 1994|volume= 33| issue=13|pages= 1315–1331| doi=10.1002/anie.199413151}} 2 : Isocyanides|Trifluoromethyl compounds |
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