“C55-isoprenyl pyrophosphate”的意思、由来-开放百科全书

词条

C55-isoprenyl pyrophosphate

释义

References

{{chembox
| Verifiedfields = changed
| Watchedfields = changed
| verifiedrevid = 428740460
| ImageFile = undecaprenyl pyrophosphate.png
| ImageSize = 280px
| ImageName = Skeletal formula of C55-isoprenyl pyrophosphate
| ImageFile1 = C55-isoprenyl-pyrophosphate-3D-balls.png
| ImageSize1 = 280px
| ImageName1 = Ball-and-stick model of C55-isoprenyl pyrophosphate
| IUPACName=phosphono [(2E,6E,10E,14E,18E,22E,26E,30E,34E,38E)-3,7,11,15,19,23,27,31,35,39,43-undecamethyltetratetraconta-2,6,10,14,18,22,26,30,34,38,42-undecaenyl] hydrogen phosphate
| OtherNames=C55-undecaprenyl pyrophosphate; Undecaprenyl pyrophosphate; Pyrophosphoryl undecaprenol; Undecaisoprenyl pyrophosphate; Undecaprenyl diphosphate
|Section1={{Chembox Identifiers
| CASNo_Ref = {{cascite|correct|??}}
| CASNo=31867-59-1
| PubChem=5280604
| ChEBI_Ref = {{ebicite|changed|EBI}}
| ChEBI = 17047
| KEGG_Ref = {{keggcite|changed|kegg}}
| KEGG = C03543
| ChemSpiderID_Ref = {{chemspidercite|changed|chemspider}}
| ChemSpiderID = 4444213
| SMILES = CC(=CCC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/CC/C(=C/COP(=O)(O)OP(=O)(O)O)/C)/C)/C)/C)/C)/C)/C)/C)/C)/C)C
| InChI = 1/C55H92O7P2/c1-45(2)23-13-24-46(3)25-14-26-47(4)27-15-28-48(5)29-16-30-49(6)31-17-32-50(7)33-18-34-51(8)35-19-36-52(9)37-20-38-53(10)39-21-40-54(11)41-22-42-55(12)43-44-61-64(59,60)62-63(56,57)58/h23,25,27,29,31,33,35,37,39,41,43H,13-22,24,26,28,30,32,34,36,38,40,42,44H2,1-12H3,(H,59,60)(H2,56,57,58)/b46-25+,47-27+,48-29+,49-31+,50-33+,51-35+,52-37+,53-39+,54-41+,55-43+
| InChIKey = NTXGVHCCXVHYCL-RDQGWRCRBJ
| StdInChI_Ref = {{stdinchicite|changed|chemspider}}
| StdInChI = 1S/C55H92O7P2/c1-45(2)23-13-24-46(3)25-14-26-47(4)27-15-28-48(5)29-16-30-49(6)31-17-32-50(7)33-18-34-51(8)35-19-36-52(9)37-20-38-53(10)39-21-40-54(11)41-22-42-55(12)43-44-61-64(59,60)62-63(56,57)58/h23,25,27,29,31,33,35,37,39,41,43H,13-22,24,26,28,30,32,34,36,38,40,42,44H2,1-12H3,(H,59,60)(H2,56,57,58)/b46-25+,47-27+,48-29+,49-31+,50-33+,51-35+,52-37+,53-39+,54-41+,55-43+
| StdInChIKey_Ref = {{stdinchicite|changed|chemspider}}
| StdInChIKey = NTXGVHCCXVHYCL-RDQGWRCRSA-N
|Section2={{Chembox Properties
| C=55|H=92|O=7|P=2
| Appearance=
| Density=
| MeltingPt=
| BoilingPt=
| Solubility=
|Section3={{Chembox Hazards
| MainHazards=
| FlashPt=
| AutoignitionPt=
}}

C55-isoprenyl pyrophosphate (undecaprenyl pyrophosphate) is an essential molecule involved in construction of the bacterial peptidoglycan cell wall.^[1] It is a receptor found in the plasma membrane of bacteria that allows glycan tetrapeptide monomers synthesized in the cell cytoplasm to translocate to the periplasmic space.

References

1. ^{{cite journal|first1=K. John |last1=Stone|first2= Jack L. |last2=Strominger|title=Mechanism of Action of Bacitracin: Complexation with Metal Ion and C55-Isoprenyl Pyrophosphate|journal=PNAS|volume=68|issue=12|date=December 1971|pages=3223–3227|pmid=4332017}}

2 : Organophosphates|Terpenes and terpenoids

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