词条 | 3,5-Dimethylpiperidine |
释义 |
| verifiedrevid = 399204910 | Name = 3,5-Dimethylpiperidine | ImageFile = 3,5-dimethylpiperidine.svg | ImageSize = | ImageName = Structure of 3,5-dimethylpiperidine | PIN = 3,5-Dimethylpiperidine | OtherNames = 3,5-Lupetidine |Section1={{Chembox Identifiers | PubChem = 118259 | ChemSpiderID = 105689 | SMILES = CC1CC(CNC1)C | StdInChI = 1S/C7H15N/c1-6-3-7(2)5-8-4-6/h6-8H,3-5H2,1-2H3 | StdInChIKey = IDWRJRPUIXRFRX-UHFFFAOYSA-N | CASNo = 35794-11-7 | RTECS = |Section2={{Chembox Properties | C=7 | H=15 | N=1 | Appearance = Colorless liquid | Density = 0.853 g/mL (mixture) | Solubility = Low | Solvent = other solvents | SolubleOther = Most organic solvents | MeltingPt = | BoilingPtC = 144 | pKb = | RefractIndex = 1.4454 |Section3={{Chembox Structure | Dipole = |Section7={{Chembox Hazards | ExternalSDS = | MainHazards = Flammable | FlashPtC = 33 | RPhrases = | SPhrases = |Section8={{Chembox Related | OtherCompounds = 2,6-Dimethylpiperidine Piperidine }} 3,5-Dimethylpiperidines are chemical compounds with the formula C5H8(CH3)2NH. Two diastereomers exist: the achiral R,S isomer and the chiral R,R/S,S enantiomeric pair. 3,5-Dimethylpiperidine is a precursor to tibric acid. The compound is typically prepared by hydrogenation of 3,5-dimethylpyridine. Both diastereomers also arise from the reduction of 3,5-dimethylpyridine with lithium triethylborohydride.[1] References1. ^{{cite journal|title=Reduction of isoquinoline and pyridine-containing heterocycles with lithium triethylborohydride (Super-Hydride)|author1=Blough, Bruce E.|author2=Carroll|author3=F. Ivy|journal=Tetrahedron Letters|year=1993|volume=34|pages=7239-42|doi=10.1016/S0040-4039(00)79297-5}} {{DEFAULTSORT:Dimethylpiperidine, 3,5-}} 1 : Piperidines |
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