| Diplomatic agrément/Diplomatic accreditation | Ambassador | Observations | President of Argentina | Chancellor of Germany | Term end | | 1852 | } | Ferdinand David Schlüter | Consul in Hamburg | Justo José de Urquiza | Frederick William IV of Prussia | 1853 | } |
| 1852 | } | Augusto Borchers | Consul in Bremen | Justo José de Urquiza | Frederick William IV of Prussia |
| 1853 | } | Augusto Milberg | Consul in Hamburg | Justo José de Urquiza | Frederick William IV of Prussia | 1854 | } |
| 1853 | } | Federico Eduardo Schutt | Konsul in Lübeck | Justo José de Urquiza | Frederick William IV of Prussia |
| 1855 | } | Pablo Gutike | Consul in Berlin | Justo José de Urquiza | Frederick William IV of Prussia |
| 1854 | } | Theodor Garzen | Consul in Hamburg-Altona | Justo José de Urquiza | Frederick William IV of Prussia |
| 1854 | } | HJ Harlos | Consul in Hamburg | Justo José de Urquiza | Frederick William IV of Prussia | 1856 | } |
| 1855 | } | Delfín Bonifacio Huergo Saravia | Justo José de Urquiza | Frederick William IV of Prussia |
| 1856 | } | Daniel Ley|de}} | Consul in Munich | Justo José de Urquiza | Frederick William IV of Prussia |
| 1857 | } | David Osterreich | Consul in Rhineland | Justo José de Urquiza | Frederick William IV of Prussia |
| 1858 | } | JL Wuthoff | Consul in Hamburg | Justo José de Urquiza | William I, German Emperor |
| 1860 | } | Enrique Lorens | Consul in Hamburg | Santiago Derqui | William I, German Emperor |
| 1860 | } | Jorge Richjene | Consul in Cologne (Germany) | Santiago Derqui | William I, German Emperor |
| 1862 | } | Federico Möller | Consul in Kassel. | Bartolomé Mitre | William I, German Emperor |
| 1879 | } | Mariano Balcarce | was accredited in Rome, Vienna, Brüssel and Lisbon. | Nicolás Avellaneda | William I, German Emperor |
| 1882 | } | Miguel Cané | until 1886 when Manuel García, Héctor Álvarez and Agustín Arroyo were accredited in Vienna also accredited in Vienna. | Julio Argentino Roca | William I, German Emperor |
| 1883 | } | Carlos Calvo | Julio Argentino Roca | William I, German Emperor |
| 1890 | } | Ernesto Bosch | Carlos Pellegrini | Wilhelm II, German Emperor | 1892 | } |
| 1898 | } | General Lucio V. Mansilla | 1831|12|24}}; † {{dts|1913|10|08}} in París) | Julio Argentino Roca | Wilhelm II, German Emperor |
| 1899 | } | Felipe Calvari | († 1899) | Julio Argentino Roca | Wilhelm II, German Emperor |
| 1902 | } | Vicente Gaspar Quesada|de}} | Julio Argentino Roca | Wilhelm II, German Emperor |
| 1905 | } | Martín García Mérou | 1862|10|14}} in Buenos Aires;† {{dts|1905|05|30}} in Berlín) | Manuel Quintana | Wilhelm II, German Emperor | 1905 | } |
| 1905 | } | Indalecio Gómez | Manuel Quintana | Wilhelm II, German Emperor |
| 1910 | } | Luis B. Molina | Roque Sáenz Peña | Wilhelm II, German Emperor |
| 1925 | } | Federico M. Quintana | Marcelo Torcuato de Alvear | Hans Luther |
| 1928 | } | Ernesto Restelli | 1884|04|01}}) | Hipólito Yrigoyen | Hermann Müller (politician) | 1932|09|30}} |
| 1932 | } | Eduardo Labougle Carranza|de}} | Agustín Pedro Justo | Franz von Papen | 1939 | } |
| 1939 | } | Ricardo Olivera (1886–1949)|de}} | Roberto María Ortiz | Adolf Hitler | 1942 | } |
| 1942 | } | Luis Santiago Luti|de}} | Charge d Affairs | Ramón Castillo | Adolf Hitler | 1944|01|29}} |
| 1950 | } | Luis Herman Irigoyen | Juan Perón | Konrad Adenauer |
| 1952 | } | Luis Herman Irigoyen | Juan Perón | Konrad Adenauer | 1956 | } |
| 1956 | } | Eduardo Labougle Carranza|de}} | Eduardo Lonardi | Konrad Adenauer | 1957 | } |
| 1957 | } | Carlos Indalecio Gomez | Eduardo Lonardi | Konrad Adenauer | 1958 | } |
| 1958 | } | Hector D'Andrea | Arturo Frondizi | Konrad Adenauer | 1959 | } |
| 1959 | } | Gualterio Enrique Ahrens|de}} | Arturo Frondizi | Konrad Adenauer | 1963 | } |
| 1964 | } | Luis Herman Irigoyen | Arturo Umberto Illia | Ludwig Erhard | 1970 | } |
| 1971 | } | Enrique Ruiz Guiñazú y Cantilo | 1909|02|20}}) | Alejandro Agustín Lanusse | Willy Brandt | 1973 | } |
| 1973 | } | Rafael Maximiliano Vasquez | Héctor José Cámpora | Willy Brandt | 1975 | } |
| 1976 | } | Enrique Ruiz Guiñazú y Cantilo | Jorge Rafael Videla | Helmut Schmidt | 1978 | } |
| 1978 | } | Roberto Enrique Guyer | Jorge Rafael Videla | Helmut Schmidt | 1984 | } |
| 1984 | } | Hugo Boatti Ossorio | Raúl Alfonsín | Helmut Kohl | 1989 | } |
| 1989 | } | Carlos Alfredo Mandry | Carlos Menem | Helmut Kohl | 1991 | } |
| 1991 | } | Roberto Enrique Guyer | Carlos Menem | Helmut Kohl | 1994 | } |
| 1994 | } | Carlos Oscar Keller Sarmiento | Carlos Menem | Helmut Kohl | 1998 | } |
| 1998|09|02}} | Andrés Guillermo Pesci Bourel | 2005|07|11}}) | Carlos Menem | Helmut Kohl | 2000 | } |
| 2000 | } | Enrique J.A. Candioti | Fernando de la Rúa | Gerhard Schröder | 2006 | } |
| 2006 | } | Guillermo Nielsen | 1951|04|20}} in Buenos Aires) | Néstor Kirchner | Angela Merkel |
| 2010 | } | Victorio Taccetti | 1943|01|22}} in Buenos Aires) | Cristina Fernández de Kirchner | Angela Merkel |
| 2013|09|06}} | Daniel Adán Dziewezo Polski | 2005|07|31}} to {{dts|2010|01|01}}de 2010 he was Argentine Ambassador to Japan[1] | Cristina Fernández de Kirchner | Angela Merkel |
{{coord|52.501162|13.344672|display=title|region:BO_type:landmark||}}1. ^ [https://www.diplomatisches-magazin.de/ambassador/&bsid=223 Daniel Adán Dziewezo Polski]
2. ^{{Ill|Tobias C. Bringmann|de}}, Handbuch der Diplomatie 1815-1963: Auswärtige Missionschefs in Deutschland [https://books.google.de/books?id=pXWJpFbz1AoC&pg=PA14&dq=%22Sohn+des+argent.+Pr%C3%A4sidenten+Hip%C3%B3lito+Irigoyen+(1850-1933),+der+zweimal+1916/22+und+1928/30+an+der+Spitze+der+Republik+stand+und+dessen+vers%C3%B6hnliche+Haltung+im+Sommer+1917+einen+antideutschen+Kriegseintritt+Argentiniens+aufgrund%22&hl=de&sa=X&redir_esc=y#v=onepage&q=%22Sohn%20des%20argent.%20Pr%C3%A4sidenten%20Hip%C3%B3lito%20Irigoyen%20(1850-1933)%2C%20der%20zweimal%201916%2F22%20und%201928%2F30%20an%20der%20Spitze%20der%20Republik%20stand%20und%20dessen%20vers%C3%B6hnliche%20Haltung%20im%20Sommer%201917%20einen%20antideutschen%20Kriegseintritt%20Argentiniens%20aufgrund%22&f=false p. 14]
3. ^Ibero-American Institute,