“Bodroux–Chichibabin aldehyde synthesis”的意思、由来-开放百科全书

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Bodroux–Chichibabin aldehyde synthesis

释义

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The Bodroux–Chichibabin aldehyde synthesis is a chemical reaction whereby a Grignard reagent is converted to an aldehyde one carbon longer.

Reaction of a Grignard reagent with triethyl orthoformate gives an acetal, which can be hydrolyzed to an aldehyde. For example, the synthesis of n-hexanal:^[1]

References

1. ^¹{{OrgSynth | title = n-Hexaldehyde | author = G. Bryant Bachman | collvol = 2 | collvolpages = 323 | year = 1943 | prep = CV2P0323}}

*{{cite journal | author = Bodroux, F. | journal = Compt. Rend. | year = 1904 | volume = 138 | pages = 92 | title = Synthése d'aldehydes aromatiques | language = French | trans-title = Synthesis of aromatic aldehydes | url = http://gallica.bnf.fr/ark:/12148/bpt6k3092p/f98.image.r=Bodroux}}

{{cite journal | journal = Ber. | year = 1904 | volume = 37 | pages = 186 | doi = 10.1002/cber.19040370133 | title = Eine neue allgemeine Darstellungsmethode der Aldehyde | language = German | author = Tschitschibabin, A. E.}}
{{cite journal | journal = Ber. | year = 1904 | volume = 37 | pages = 850 | doi = 10.1002/cber.190403701140 | title = Ueber den Hexahydro-m-toluylaldehyd | language = German | author = Tschitschibabin, A. E.}}
{{cite journal | author1 = Smith, L. I. | author2 = Bayliss, M. | title = The Bodroux-Tschitschibabin, and the Bouveault Aldehyde Syntheses | journal = J. Org. Chem. | year = 1941 | volume = 6 | pages = 437 | doi = 10.1021/jo01203a009 | issue = 3}}
{{cite journal | author1 = Smith, L. I. | author2 = Nichols, J. | title = The Synthesis of Aldehydes from Grignard Reagents. II. Polymethylbenzaldehydes | journal = J. Org. Chem. | year = 1941 | volume = 6 | pages = 489 | doi = 10.1021/jo01204a003 | issue = 4}}

3 : Carbon-carbon bond forming reactions|Name reactions|Formylation reactions

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